Xenon
| Other names/abbreviations: |
Xe |
| Element no: |
54 |
| Element group: |
18 (IUPAC) VIII A (American labelling) VIII B (European labelling) Noble gasses |
| Element type: |
Nonmetals |
| CAS-Number: |
7440-63-3 |
| EINECS-Number: |
231-172-7 |
Chemical properties
Reaction of xenon with acids
Xenon does not react with acids.
Reaction of xenon with air
Xenon does not react with air.
Reaction of xenon with bases
Xenon does not react with bases.
Reaction of xenon with halogens
Xenon can be brought to react with fluorine, F
2 [4]:
Xe(g) + 2 F
2(g)

XeF
4(s), mix gasses at 400°C then cool to -78°C
Xe(g) + F
2(g)

XeF
2(s)
Xe(g) + 3 F
2(g)

XeF
6(s)
The xenon fluorides are used for synthesis of other xenon compounds [4].
Reaction of xenon with the water
Xenon does not react with water but dissolves slightly; approximately 108.1 cm
3/kg at 20°C [1].
Solubility
Water: 108.1 cm
3/L (Approximately, 20°C) [3]
Safety
Symbol: -
R-phrases: -
S-phrases: -
Physical properties
Appearance
|
|
Physical state @ 20°C: |
Gas [3] |
|
Color: |
Colourless [3] |
Bulk properties
|
|
Molecular weight (g/mol): |
131.29(2) [1] |
|
Melting point (°C): |
-111.75 [2] |
|
Boiling point (°C): |
-108.04 [2] |
|
Density (g/cm3): |
0.0058971 [1] |
|
Molar volume (cm3): |
35.92 |
|
Velocity of sound (m/s): |
1090 |
Optical properties
|
|
Refractive index: |
1.000702 |
Thermodynamic properties
|
|
ΔfH°gas (kJ/mol): |
0.0 [2] |
|
ΔfH°fusion (kJ/mol): |
1.81 [2]
|
|
S°gas (J/mol): |
169.7 [2]
|
|
Cp (gas) (J/mol·K): |
20.786 (25 °C) [2]
|
|
Critical temperature (°C): |
16.58 [2]
|
Electronic properties
|
 |
Electron configuration: |
1s2-2s2-2p6-3s2-3p6-4s2-3d10-4p6-4d10-5s2-5p6 | |
Conductivity
|
|
Thermal (W/m·K): |
0.00506 [1] |
Misc.
|
|
Vapour pressure (Pa): |
4189600 (20°C) [3] |
Occurence, isolation & synthesis
Isolation
Xenon is produced by fractional destillation of liquid air [4].
References
1: Greenwood,N.N., Earnshaw,A. Chemistry of the elements
2
nd edition (1997) Edited by Greenwood,N.N., Earnshaw,A. pp. 1-1340, Butterworth-Heinemann. Oxford. Great Britain
2: CRC Handbook of Chemistry and Physics
75
th edition (1994) Edited by Lide,D.R. , CRC Press Inc. Boca Raton, USA
3: Merck. ChemDAT The Merck Chemical Database Ver. 1.1.5
4: General chemistry
7
th edition (1984) Edited by Holtzclaw, Jr.,H.F., Robinson,W.R. & Nebergall,W.H. pp. 1-932. D.C. Heath and Company. Lexington
© Michael Pilgaard
Created: March 7, 2008
Last update: October 9, 2008